Sharpless epoxidation pdf file

9.6.2.1 Sharpless Epoxidation The power of the Sharpless epoxidation methodology for allyl alcohols lies in the ability to control the facial selectivity of the reaction.14,15 The product 2,3-epoxy alcohols can be used in a wide variety of reactions. 4,16 Enantioreversal in the Sharpless Asymmetric Epoxidation Reaction Controlled by the Molecular Weight of a Covalently Appended Achiral Polymer Neal N. Reed, Tobin J. Dickerson, Grant E. Boldt, and Kim D. Janda* Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037 [email protected] Received File:Sharpless epoxidation DE.svg. From Wikimedia Commons, the free media repository. File. File history. File usage on Commons. File usage on other wikis. Size of this PNG preview of this SVG file: 743 × 486 pixels. Other resolutions: 320 × 209 pixels | 640 × 419 pixels | 1,024 × 670 pixels | 1,280 × 837 pixels | 2,560 × 1,675 pixels. The titanium tetraisoproxide catalyzed asymmetric epoxidation of allylic alcohols using tert‐butylperoxide as oxidant to yield predictable stereochemistry in the presence of an enantiomerically pure